Q[8] large-duct supermolecule self-assembly body and synthesizing method thereof

一类八元瓜环大孔道超分子自组装体及其合成方法

Abstract

The invention discloses a Q[8] large-duct supermolecule self-assembly body and synthesizing method thereof, and belongs to the technical field of covalent organic framework polymers. The Q[8] large-duct supermolecule self-assembly body is formed by the induction with transition metal ions. The formation general formula is Q[8].2[MC14].4H3O.aH2O, wherein M represents transition metal ions, and a represents the quantity of crystallized water molecules, and is greater than or equal to 51 and less than or equal to 68. The invention discloses a synthesizing method of the Q[8] large-duct supermolecule self-assembly body. The method has the characteristics that operation is simple and cycle is short.
本发明一类八元瓜环大孔道超分子自组装体及其合成方法,属共价有机框架聚合物技术领域,是由过渡金属离子诱导生成的八元瓜环Q[8]大孔道超分子自组装体,其组成通式为:Q[8]·2[MCl4]·4H3O·aH2O,M代表过渡金属离子,a为结晶水分子数量51≤a≤68。本发明公开了八元瓜环Q[8]大孔道超分子自组装体的合成方法,方法具有操作简单,周期短的特点。

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