Q[8] large-duct supermolecule self-assembly body and synthesizing method thereof



The invention discloses a Q[8] large-duct supermolecule self-assembly body and synthesizing method thereof, and belongs to the technical field of covalent organic framework polymers. The Q[8] large-duct supermolecule self-assembly body is formed by the induction with transition metal ions. The formation general formula is Q[8].2[MC14].4H3O.aH2O, wherein M represents transition metal ions, and a represents the quantity of crystallized water molecules, and is greater than or equal to 51 and less than or equal to 68. The invention discloses a synthesizing method of the Q[8] large-duct supermolecule self-assembly body. The method has the characteristics that operation is simple and cycle is short.




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Patent Citations (6)

    Publication numberPublication dateAssigneeTitle
    CN-102153574-AAugust 17, 2011贵州大学过渡金属离子诱导合成的五元瓜环-稀土金属网状超分子聚合物及其合成方法
    CN-102516550-AJune 27, 2012贵州大学Seven-membered cucurbituril-rare earth metal linear tubular supramolecular polymer, preparation and application thereof
    CN-102936258-AFebruary 20, 2013贵州大学四氯锌酸根诱导的七元瓜环-稀土管状聚合物及合成方法
    CN-102936259-AFebruary 20, 2013贵州大学Method for synthesizing cucurbit [6] uril, Q[6]-rear earth linear polymer and separating light rear earth from heavy rear earth
    KR-20070039280-AApril 11, 2007광주과학기술원Preparation of metal oxide nano-particles
    US-2008182834-A1July 31, 2008Newsouth Innovations Pty LimitedMulti-Nuclear Metal Complexes Partially Encapsulated by Cucurbit[7-12]Urils

NO-Patent Citations (4)

    LI-LI LIANG等,: "Construction of Cucurbit[7]uril Based Tubular Nanochannels Incorporating Associated [CdCl4]2- and Lanthanide Ions", 《INORG. CHEM.》, 29 January 2013 (2013-01-29), pages 1909 - 1915
    XIN XIAO等,: "Hexagonal framework based on heterometallic zinc and potassium ions/cucurbit[5]uril capsules", 《JOURNAL OF MOLECULAR STRUCTURE》, 17 February 2010 (2010-02-17), pages 216 - 219, XP026978896
    XING FENG等,: "A novel two-dimensional network formed by complexation of cucurbituril with cadmium ions", 《INORGANIC CHEMISTRY COMMUNICATIONS》, 4 July 2009 (2009-07-04), pages 849 - 852, XP026544135, DOI: doi:10.1016/j.inoche.2009.06.036
    肖昕等,: "十甲基五元瓜环与几种金属离子配合物的晶体结构", 《无机化学学报》, 30 April 2009 (2009-04-30), pages 596 - 601

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    Publication numberPublication dateAssigneeTitle